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Proton-Induced, Reversible Evolution of O2 from the OsIV–Sulfoximido Complex [OsIV(tpy)(Cl)2{NS(O)-3,5-Me2C6H3}]

✍ Scribed by My Hang V. Huynh; David E. Morris; Peter S. White; Thomas J. Meyer


Book ID
101369242
Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
115 KB
Volume
114
Category
Article
ISSN
0044-8249

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Proton-Induced, Reversible Evolution of
✍ My Hang V. Huynh; David E. Morris; Peter S. White; Thomas J. Meyer 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 114 KB

O 2 activation in biological systems is a key step in respiration with O 2 activation achieved by a complex series of steps involving binding to an Fe ± heme, electron transfer, and, ultimately, atom transfer to a reducing substrate. Kinetic difficulties in the electroreduction of O 2 to H 2 O in f