✦ LIBER ✦

Proton hyperfine data and temparature dependence of the dynamics of ring rotation in bis-benzene-vanadium: a powder endor study

✍ Scribed by A. Schweiger; R. Wolf; Hs.H. Günthard; J.H. Ammeter; E. Deiss

Publisher: Elsevier Science
Year: 1980
Tongue: English
Weight: 513 KB
Volume: 71
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(80)85302-4

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✦ Synopsis

The quasi-free benzene rotation of paramagnetx V(CeH& substituted mto Fe(CsH& and Cr(C,&h hosts has been studled by ENDOR spectcoscopy between T = 15 K and T = 180 K. In Fe(CsH&, two different coalescence temperatmes have been found The full proton hfs tensor of the ngd molecule has been determined from powder samples.