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Proton Exchange Reaction between Hydroxyl Groups in the Supercage and Those in the Sodalitecage of Y Zeolite As Studied by Variable Temperature 1 H MAS NMR

โœ Scribed by Asakawa, Naoki; Motokura, Ken; Yashima, Tatsuaki; Koyama, To-ru; O-nuki, Toshinori; Miyaji, Akimitsu; Baba, Toshihide


Book ID
120358185
Publisher
American Chemical Society
Year
2012
Tongue
English
Weight
494 KB
Volume
116
Category
Article
ISSN
1932-7447

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The temperature dependence of the line-shape of 1H MAS NMR spectra of H-mordenite and H-MCM-22 was examined. Upon raising the temperature of measurements stepwise from 298 to 503 K, the line-width of 1H MAS NMR of acidic protons in H-mordenite with SiO 2 /Al 2 O 3 ratio of 106 increased, went throug