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Proton exchange in coordinated sulfoxide ligands

โœ Scribed by Dale A. Johnson


Book ID
103110489
Publisher
Elsevier Science
Year
1969
Weight
152 KB
Volume
5
Category
Article
ISSN
0020-1650

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Ligand exchange reaction of sulfoxides i
โœ Tsuyoshi Satoh; Noriko Yamada; Tohru Asano ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 206 KB

Reaction of [3-mesyloxy sulfoxides, derived from alkyl (or arylmethyl) phcnyl sulfoxides and aldehydes in two steps, with alkylmetal (n-BuLl, t-BuLi, or EtMgBr) at -78 ยฐC gave olefins in good to excellent yields. This reaction offers a sulfoxlde version of the Juha-Lythgoe olefination.