✦ LIBER ✦
Proton elimination in charge-separation reactions with hydrogen halides driven by chemical-bond formation with triply-charged C60 cations
✍ Scribed by Vladimir Baranov; Diethard K. Bohme
- Book ID
- 103036771
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 253 KB
- Volume
- 258
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
Experimental results are reported which demonstrate the efficient elimination of protons in charge-separation reactions of C~ + with HCI and HBr at room temperature. Two mechanisms are observed for the production of protons in these ion/molecule reactions: dissociative electron transfer and halide transfer with concomitant chemical-bond formation. Both occur in the reaction with HBr which produces protons in all reactive collisions.