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Proton double quantum coherence and cross-relaxation in (NH4)2SnBr6

✍ Scribed by M. Punkkinen; A. Kaikkonen; E.E. Ylinen; M. Kankaanpää; A.H. Vuorimäki

Publisher
Elsevier Science
Year
1998
Tongue
English
Weight
146 KB
Volume
13
Category
Article
ISSN
0926-2040

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✦ Synopsis

A proton double quantum coherence signal can be observed exclusively from the T species NH4 groups (with the total spin I = 1) in ammonium compounds at low temperatures by the three-pulse sequence 90x degrees - tpr - 90x degrees - tev - 90x degrees - ta, where tpr and ta are of the magnitude of the inverse line width and tev very short. The usefulness of this pulse sequence, preceded by the additional pulse sequence 90x degrees - t1 -90(-x) degrees - t2 for creating an unbalance between the A and T species magnetizations, was demonstrated by applying it to cross-relaxation studies in (NH4)2SnBr6.

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