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Proton-Coupled Electron Transfer from Sulfur: A S-H/S-D Kinetic Isotope Effect of ≥31.1

✍ Scribed by My-Hang V. Huynh; Peter S. White; Thomas J. Meyer

Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
111 KB
Volume
39
Category
Article
ISSN
0044-8249

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✦ Synopsis

There is an extensive redox chemistry of high oxidation state ruthenium(iv) oxo, [1] and osmium(vi) nitrido, [2] and osmium(iv ± vi) hydrazido [3] complexes based on multiple electron/atom transfers such as O atom, [4] N À ion, [3] and H À

[2]Cl 6 ´16 H 2 O: To a solution of Na[AuCl 4 ] (0.10 g, 0.28 mmol) in water (2 mL) was added 2,2'-thiodiethanol (0.16 mL). The resulting colorless solution was added to a solution of [1]Cl 2 ´5 H 2 O (0.20 g, 0.24 mmol) in water (40 mL). The mixture was stirred at RT for 30 min, followed by addition of several drops of a saturated NaCl aqueous solution. The reaction solution was allowed to stand at RT for 5 days, which gave dark green-brown microcrystals. Yield: 0.22 g (82 %); elemental analysis for [Au 2 {Pd[Co(C

📜 SIMILAR VOLUMES

Proton-Coupled Electron Transfer from Su
Proton-Coupled Electron Transfer from Sulfur: A S-H/S-D Kinetic Isotope Effect of ≥31.1
✍ My-Hang V. Huynh; Peter S. White; Thomas J. Meyer 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 112 KB 👁 1 views

There is an extensive redox chemistry of high oxidation state ruthenium(iv) oxo, [1] and osmium(vi) nitrido, [2] and osmium(iv ± vi) hydrazido [3] complexes based on multiple electron/atom transfers such as O atom, [4] N À ion, [3] and H À [2]Cl 6 ´16 H 2 O: To a solution of Na[AuCl 4 ] (0.10 g, 0.