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Proton coordination by polyamine compounds in aqueous solution

✍ Scribed by Andrea Bencini; Antonio Bianchi; Enrique; Mauro Micheloni; José Antonio Ramirez

Publisher: Elsevier Science
Year: 1999
Tongue: English
Weight: 746 KB
Volume: 188
Category: Article
ISSN: 0010-8545
DOI: 10.1016/s0010-8545(98)00243-4

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✦ Synopsis

The present article is concerned with proton transfer reactions in aqueous solution of open-chain, macrocyclic and macropolycyclic or cage compounds having nitrogen atoms as protonation sites in the molecular framework, although several compounds with additional different donors will be considered. The main purpose of this review is to collect some significant examples of proton transfer processes in order to show how the electronic properties and molecular topology of polyamines affect the thermodynamic parameters of their protonation equilibria.

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