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Proton catalyzed hydrolytic deamination of cytosine: a computational study

โœ Scribed by V. Labet; A. Grand; C. Morell; J. Cadet; L. A. Eriksson


Book ID
105886196
Publisher
Springer
Year
2008
Tongue
English
Weight
372 KB
Volume
120
Category
Article
ISSN
1432-2234

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Hydrolytic degradation of ฮฑ-substituted
โœ Lawrence M. Pratt; C.C. Chu ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 850 KB

The two-step hydrolyses of substituted polyglycolic acids are modeled by the semiempirical MNDO Hamiltonian using small molecule analogs to determine the effect of the alkyl substituents on the reaction and activation enthalpies. Reaction enthalpies remain reasonably constant up to three carbons, be