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Proton, carbon-13, and nitrogen-15 nuclear magnetic resonance studies of [15N]azoles: 1-phenylpyrazole and the tautomerically mobile 3-methyl-1-phenylpyrazolin-5-one

✍ Scribed by Hawkes, Geoffrey E.; Randall, Edward W.; Elguero, Jos�; Marzin, Claude J.


Book ID
120168689
Publisher
Royal Society of Chemistry
Year
1977
Tongue
English
Weight
554 KB
Volume
8
Category
Article
ISSN
1472-779X

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## Abstract The influence of substituents in a new series of 2__H__‐thiopyrans, 2__H__‐thiopyran‐2‐ones (thiones) and their thiazine analogues is examined by means of carbon (^13^C) and nitrogen (^15^N) NMR. A linear relationship is shown to exist between the chemical shifts (δ~13C~ or δ~15N~) of t