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Proton and carbon-13 CIDNP study of the radical rearrangement involved in the reaction of tert-butylsulfinyl chloride with N-hydroxysulfonamides

✍ Scribed by Bleeker, Ido P.; Engberts, Jan B. F. N.

Book ID
118057266
Publisher
American Chemical Society
Year
1981
Tongue
English
Weight
400 KB
Volume
46
Category
Article
ISSN
0022-3263

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## Abstract __tert__‐Butylsulfinyl chloride (**1**) reacts smoothly with __N__′‐(di)methyl‐ and __N__′‐(di)phenyl‐__N__‐hydroxyurea (**2**) in acetone at room temperature, in the presence of two equivalents of pyridine. An intermediate __O‐tert__‐butylsulfinyl‐__N__‐hydroxyurea (**3**) is postulate

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