Protein Control of Electron Transfer Rates via Polarization: Molecular Dynamics Studies of Rubredoxin
β Scribed by Dolan, Elizabeth A.; Yelle, Robert B.; Beck, Brian W.; Fischer, Justin T.; Ichiye, Toshiko
- Book ID
- 118516058
- Publisher
- Biophysical Society
- Year
- 2004
- Tongue
- English
- Weight
- 157 KB
- Volume
- 86
- Category
- Article
- ISSN
- 0006-3495
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π SIMILAR VOLUMES
In the analysis of kinetic data from multicentre redox proteins, it is essential to distinguish between the observable macroscopic rate constants and the structurally relevant microscopic properties. This distinction is complicated by the existence of interactions between centres. The problem is ill
The present work rests on non-adiabatic electron transfer theory. The influence of the molecular dynamics (MD) of exchanging groups on the electron transfer rate is treated. The MD of exchanging groups is described as a stochastic process with two possible states. The transfer between these two stat