Prostaglandins and congeners. 18. Synthesis of cyclopentenolone precursors to prostaglandins from 2,5-dihydro-2,5-dimethoxyfurans
β Scribed by Floyd, M. Brawner
- Book ID
- 120085063
- Publisher
- American Chemical Society
- Year
- 1978
- Tongue
- English
- Weight
- 425 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0022-3263
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## Abstract Oxindole 11, obtained on 3β[2β²β(dimethylamino)ethyl]alkylation of oxindole 12, yielded, on stereoselective reduction with sodium dihydridobis(2βmethoxyethoxy)aluminate, aminoalcohol 8 (__Scheme 2__). The quaternary methiodide 10, obtained from 8 with MeI, gave, in nucleophilic displacem