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Prostaglandin synthesis. 12. Synthesis of (7E)- and (7Z)-punaglandin 4. Structural revision

✍ Scribed by Suzuki, M.; Morita, Y.; Yanagisawa, A.; Noyori, R.; Baker, Bill J.; Scheuer, Paul J.

Book ID
121227685
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
295 KB
Volume
108
Category
Article
ISSN
0002-7863

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## Abstract A synthesis of the title aldehyde 1 and acid 2, the (__R__) enantiomers of the antifungal and antibacterial principles of __Sporothrix__ species, was developed. Alkylation of the alkynol derivative 6 with (__S__)‐citronellyl bromide (5), depyranylation, __cis__ hydrogenation, PCC oxidat