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Proposition for a new definition of the chiral plane and its consequences for the specification of planar chirality

✍ Scribed by Lemiere, Guy L.; Alderweireldt, Frank C.


Book ID
121432406
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
607 KB
Volume
45
Category
Article
ISSN
0022-3263

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Chiral Rh- and Ir-catalyzed intramolecul
✍ Takanori Shibata; Tatsuya Chiba; Hiroyuki Hirashima; Yasunori Ueno; Kohei Endo πŸ“‚ Article πŸ“… 2011 πŸ› John Wiley and Sons 🌐 English βš– 204 KB

## Abstract Enantioselective intramolecular cycloaddition of hexaynes with 1,3‐diyne moiety was examined. Chiral Rh catalyst provided axially chiral 1,1β€² ‐bis(biphenylenyl) derivatives by consecutive [2+2+2] cycloaddition. In contrast, chiral Ir catalyst provided axially chiral macrocyclic compound