๐”– Bobbio Scriptorium
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Properties of glass-filled thermoplastic polyesters

โœ Scribed by B. J. Chisholm; P. M. Fong; J. G. Zimmer; R. Hendrix


Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
229 KB
Volume
74
Category
Article
ISSN
0021-8995

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โœฆ Synopsis


The thermal, mechanical, and rheological properties of glass-filled poly(propylene terephthalate) (GF PPT) were compared to glass-filled poly(butylene terephthalate) (GF PBT). The impetus for this study was the recent commercial interest in PPT as a new glass-reinforced thermoplastic for injection-molding applications. This article represents the first systematic comparison of the properties of GF PPT and GF PBT in which differences in properties can be attributed solely to differences in the polyester matrices, that is, glass-fiber size and composition, polymer melt viscosity, nucleant content and composition, polymerization catalyst composition and content, and processing conditions were kept constant. Under these controlled conditions, GF PPT showed marginally higher tensile and flexural properties and significantly lower impact strength compared to GF PBT. The crystallization behavior observed by cooling from the melt at a constant rate showed that GF PBT crystallized significantly faster than did GF PPT. Nucleation of GF PPT with either talc or sodium stearate increased the rate of crystallization, but not to the level of GF PBT. The slower crystallization rate of GF PPT was found to strongly affect thermomechanical properties of injection-molded specimens. For example, increasing the polymer molecular weight and decreasing the mold temperature significantly increased the modulus drop associated with the glass transition. In contrast, the modulus-temperature response of GF PBT was just marginally influenced by the polymer molecular weight and was essentially independent of the mold temperature.


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