A solid-state lithium-polypyrrole cell having a polymeric electrolyte based on the lithium perchlorate-poly(ethylene oxide) complex, has been assembled. Results based on cyclic voltammetry, frequency response analyses and charge-discharge cycles, show that the polymer/polymer interface is characteri
Properties of electrochemically synthesized polymer electrodes—IX. The effects of surfactants on polypyrrole films
✍ Scribed by S. Panero; P. Prosperi; B. Scrosati
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 484 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0013-4686
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✦ Synopsis
The electrochemical behaviour of polypyrrole film electrodes synthesized in the presence of sodium dodecylsulphate, has been investigated by cyclic voltammetry and frequency response analysis. The results indicate that the surfactant anion favours redox processes which are faster and more reversible than those associated to usual polypyrrole electrodes. The modified, surfactant-based polypyrrole electrodes have been successfully used in lithium, organic electrolyte batteries having improved power density and cyclability characteristics.
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