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Properties of a new ferroelectric crystal family: MCd(NO2)3[M=NH4, K, Rb, Cs, Tl]

✍ Scribed by Klaus Planta; Hans-Günther Unruh

Book ID
112516208
Publisher
Springer
Year
1993
Tongue
English
Weight
553 KB
Volume
92
Category
Article
ISSN
1434-6036

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Blue crystals of metal nitratocuprates(II), M 3 [Cu(NO 3 ) 4 ](NO 3 ) (M = K (I), NH 4 (II), Rb (III)) and Cs 2 [Cu(NO 3 ) 4 ] (IV) were synthesized from Cu(NO 3 ) 2 3 H 2 O and MNO 3 by heating at 100±140 °C during 3±12 h. X-ray single crystal structures for isotypic I and II reveal the presence of