Radiation graft copolymerization of comonomer mixtures of acrylic acid (AAc) and styrene (S) onto polypropylene (PP) Γlms by the mutual method has been investigated. The e β ect of di β erent factors that may a β ect the grafting yield, such as inhibitor concentration (MohrΓs salt), solvent composition
Properties and biocompatibility of polypropylene graft copolymer films
β Scribed by El-Rehim, H. A. Abd ;El-Arnaouty, M. B.
- Publisher
- John Wiley and Sons
- Year
- 2004
- Tongue
- English
- Weight
- 242 KB
- Volume
- 68B
- Category
- Article
- ISSN
- 0021-9304
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β¦ Synopsis
Modifying the surfaces of polymers has received a great deal of attention, because it could bring about specific surface characteristics such as antithrombogenic property. Therefore, N-vinyl pyrrolidone/sodium acrylate (NVP/Na-AAc) binary monomers were introduced onto polypropylene (PP) films by a radiation grafting method. The effect of solvent and comonomer composition on the degree of grafting was determined. Studies of the mechanical properties and water content of such graft copolymers showed that as the grafting yield increases the elongation percent decreases. However, the water content increases with increasing grafting yield. The blood compatibility of the original PP and PP-g-NVP/Na-AAc films was evaluated by determination of the extent of platelet adsorption and thrombus formation. The blood compatibility of PP-g-NVP/Na-AAc seems to be better than that of original PP.
π SIMILAR VOLUMES
Direct radiation-induced grafting of acrylonitrile (AN) onto both isotactic polypropylene (IPP) and (tetrafluoroethylene-ethylene) copolymer (ET) films has been studied. The effect of grafting conditions such as inhibitor and monomer concentrations and irradiation dose on the grafting yield was inve