We have made a precise study of the circular polarisation of rotationally resolved features of laserexcited iodine. The J' = 19,u'=161evelof3~~u was excited using circularly polarised dye-laser fluorescence and a quantitative data on polarisation features representing inelastic transfer of AJ' = 30
Propensity rules in rotationally inelastic collisions of CO2
β Scribed by Millard H. Alexander; D.C. Clary
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 454 KB
- Volume
- 98
- Category
- Article
- ISSN
- 0009-2614
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We show that oscillations in thechattering region, in plots offmal rotational aciion (Jr), collision time (T) and scattering angle (x) as functions of initial rotational phase (0,) ofthe diatom in planar Li-FH rlgid rotor colhsions for fixed initial impact parameter (h) values, exhibit a behavior th
The first direct experimental evidence is reported of large orientation (head-tail) effects in rotationally inelastic collisions, lfor the specific case of NO and Ar. NO is selected in the 2II~/2 j = 2 state and oriented in an electric field. The steric effect, measured for collisions to three disti