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Propene homo- and copolymerization using homogeneous and supported metallocene catalysts based on Me2Si(2-Me-Benz[e]lnd)2ZrCl2

✍ Scribed by Stephan Jüngling; Sebastian Koltzenburg; Rolf Mülhaupt

Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
368 KB
Volume
35
Category
Article
ISSN
0887-624X

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✦ Synopsis

The isoselective propene polymerization using the supported catalyst SiO 2 /MAO/ Me 2 Si(2-Me-Benz[e]Ind) 2 ZrCl 2 /AlR 3 was investigated and compared with propene polymerization using the corresponding homogeneous catalyst system. The influence of propene concentration, polymerization medium, temperature, comonomer, and external aluminium alkyls on polymerization kinetics and polypropene properties such as molecular mass, stereo-and regioselectivity, morphology, and bulk density was studied.

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