The title diketone has been prepared by a synthetic sequence beginning with decane-1 ,lo-dicarboxylic acid. Introduction. -We wanted to obtain the diketone 8a mentioned in the title in order to attempt the threading of the 22-membered ring in a derivative thereof with an aliphatic chain [2]. The si
Propellanes. Part LXXXIV. Reduction of [20.3.3]propellane-24,27-dione: The three isomeric [20.3.3]propellane-24,27-diols
β Scribed by Pnina Ashkenazi; Olga Weinberg; Andrei Zlota; David Ginsburg
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 170 KB
- Volume
- 105
- Category
- Article
- ISSN
- 0165-0513
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π SIMILAR VOLUMES
A spherical cyclic diester has been prepared from the title components, separated from by-products , and purified by aid of double labelling of the components with "H and '&C. respectively. The product may be viewed as a doubly-anchored rotaxane. Introduction. -We mentioned our intention of using a
## Abstract Each of the three isomeric[4.3.3]propellaneβ8,11βdiols was lactonized by using 1, Οβdiacids of different chain lengths. The minimal chain length required to bridge the __syn__β__syn__ diol is βCO(CH~2~)~11~COβ.