## Abstract The title compounds have been isolated and their structures determined by X‐ray crystallography. Their relative stability is discussed in terms of theory and experiment. The __endo__‐adduct is the thermodynamically more stable one.
✦ LIBER ✦
Propellanes. LXVI. Exo- and Endo-Diels-Alder adducts of 4-substituted 1,2,4-triazoline-3, 5-diones with various 1, 6-methano [10]annulenes
✍ Scribed by Pnina Ashkenazi; Menachem Kaftory; David Ginsburg
- Publisher
- John Wiley and Sons
- Year
- 1983
- Tongue
- German
- Weight
- 177 KB
- Volume
- 66
- Category
- Article
- ISSN
- 0018-019X
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✦ Synopsis
Abstract
Relatively few exo‐adducts have been obtained from the title compounds. Only one such mono‐adduct, 3, is known. Several exo‐endo‐bis‐adducts have been obtained but the structure of one of these, 5, has been proved unequivocally by X‐ray structural determination.
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## Abstract Reactions of 11‐substituted‐1, 6‐methano [10]annulenes and 1, 6‐methano [10]‐annulenes substituted in the aromatic ring with the title dienophile are described.
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