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Propellanes. LXVI. Exo- and Endo-Diels-Alder adducts of 4-substituted 1,2,4-triazoline-3, 5-diones with various 1, 6-methano [10]annulenes

✍ Scribed by Pnina Ashkenazi; Menachem Kaftory; David Ginsburg


Publisher
John Wiley and Sons
Year
1983
Tongue
German
Weight
177 KB
Volume
66
Category
Article
ISSN
0018-019X

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✦ Synopsis


Abstract

Relatively few exo‐adducts have been obtained from the title compounds. Only one such mono‐adduct, 3, is known. Several exo‐endo‐bis‐adducts have been obtained but the structure of one of these, 5, has been proved unequivocally by X‐ray structural determination.


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Propellanes. LXII. The endo- and exo-add
✍ P. Ashkenazi; M. Kaftory; D. Arad; Y. Apeloig; D. Ginsburg 📂 Article 📅 1981 🏛 John Wiley and Sons 🌐 German ⚖ 174 KB

## Abstract The title compounds have been isolated and their structures determined by X‐ray crystallography. Their relative stability is discussed in terms of theory and experiment. The __endo__‐adduct is the thermodynamically more stable one.