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Propagation rate coefficients from electron spin resonance studies of the emulsion polymerization of methyl methacrylate

✍ Scribed by Ballard, Mathew J.; Gilbert, Robert G.; Napper, Donald H.; Pomery, Peter J.; O'Sullivan, Paul W.; O'Donnell, James H.


Book ID
124167422
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
807 KB
Volume
19
Category
Article
ISSN
0024-9297

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## Abstract The electron paramagnetic resonance (EPR) spectrum of methyl methacrylate polymerizing in a range of systems is simulated using a consistent set of parameters for two rotamers of a single free radical. The 9‐line spectrum observed in bulk and emulsion polymerization was fitted by a supe