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Prompt NO: Theoretical prediction of the high-temperature rate coefficient for CH + N2 → HCN + N

✍ Scribed by James A. Miller; Stephen P. Walch

Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
119 KB
Volume
29
Category
Article
ISSN
0538-8066

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✦ Synopsis

flames fueled by hydrogen, carbon monoxide, and various hydrocarbons at atmospheric and higher pressures (where the primary reaction zone is confined to a very narrow region immediately adjacent to the burner), Fenimore found that his NO profiles extrapolated to zero at the burner surface in the hydrogen and carbon-monoxide flames, but they did not do so in any of the hydrocarbon flames. Moreover, this "intercept NO," or "prompt NO," increased with increasing equivalence ratio up to an equivalence ratio of approximately 1.4. Fenimore attributed the prompt NO to a reaction between a hydrocarbon radical and mol-

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