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Promoter action of alkali in the activation of CO2 on Pd(111): A HREELS case study

โœ Scribed by S. Wohlrab; D. Ehrlich; J. Wambach; H. Kuhlenbeck; H.-J. Freund

Publisher
Elsevier Science
Year
1989
Weight
49 KB
Volume
220
Category
Article
ISSN
0167-2584

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Polyethylene (PE) fdm is used as a matrix for studying temperature-dependent equilibria by IR spectroscopy; the film is impregnated with Cp%(CO)z (Cp%$-CsMes) using supercritical CO, and subsequently saturated with HORe (RF= (CFs)zCH or (CFs)sC). At 200 K, the equilibrium between Cp\*Ir(CO)z and the