## Abstract A series of α,ω‐dienes have been exposed to Ru(Cl~2~)(CHPh)(PCy~3~)~2~, [Ru] 3, metathesis catalyst under acyclic diene metathesis (ADMET) conditions, and the products were compared with those obtained previously using Schrock's well defined Mo and W alkylidenes. High molecular weight
✦ LIBER ✦
Progress toward new catalysts for acyclic diene metathesis (ADMET) polymerization reactions
✍ Scribed by Laura L. Blosch; A.Scott Gamble; James M. Boncella
- Publisher
- Elsevier Science
- Year
- 1992
- Weight
- 592 KB
- Volume
- 76
- Category
- Article
- ISSN
- 0304-5102
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## Abstract The application of the WCl~6~–e^−^–Al–CH~2~Cl~2~ system to acyclic diene metathesis polymerization of 1,9‐decadiene is reported. The polyoctenamer formed is of a weight‐average molecular weight of 9000 with a polydispersity of 1.92. IR and NMR spectral analyses indicate the retention of