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A general investigation of the elementary reactions involved in the activation processes of zirconocene and Ni-based derivatives by methylaluminoxane (MAO) was performed through the association of polymerization kinetics and spectroscopic investigation of the catalytic system. This study demonstrate
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Chromium-based heterogeneous catalysts are used exten-alkyls containing a Cp\*Cr III R fragment (Cp\* = Ξ· 5 -C 5 Me 5 , pentamethylcyclopentadienyl) catalyze the polymerization of sively for the polymerization of olefins. There are few homogeneous model systems that allow investigation of the reac-e