𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Profile and size of lone pair orbitals in CH2−, NH3− and H2O-like systems

✍ Scribed by Wai-Kee Li; Thomas C.W. Mak


Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
207 KB
Volume
25
Category
Article
ISSN
0022-2860

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Oxidation of CH3NH2 and (CH3)2NH by NiII
✍ Dror Shamir; Israel Zilbermann; Eric Maimon; Dan Meyerstein 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 121 KB

## Abstract Ni^II^(1,4,8,11‐tetraazacyclotetradecane)^2+^, Ni^II^L^2+^, is a good electrocatalyst for the oxidation of CH~3~NH~2~ and (CH~3~)~2~NH but not of (CH~3~)~3~N. The oxidation kinetics of the amines by Ni^III^L(H~2~O)~2~^3+^ indicate that the amines are good axial ligands to the tervalent

Orbital imaging of the “lone pair” elect
✍ A.O. Bawagan; C.E. Brion 📂 Article 📅 1987 🏛 Elsevier Science 🌐 English ⚖ 461 KB

The electron density in each of the outermost MOs of N( CH3)3 and NFS, as measured by electron momentum spectroscopy, is found to exhibit a very much higher degree of s character than the corresponding orbital in NHj. This behaviour is clearly predicted by MO calculations which indicate appreciable