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Products derived from the reaction of [M(CN)4O(H2O)]2− with pentane-2,4-dione. X-ray crystal structure of (Ph4P)2[M(CN)3O(acac)], M = Mo or W

✍ Scribed by Janusz Szklarzewicz; Alina Samotus; John Burgess; John Fawcett; David R. Russell


Book ID
110247261
Publisher
Springer
Year
2001
Tongue
English
Weight
130 KB
Volume
26
Category
Article
ISSN
0340-4285

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✍ Eyck-Michael Poll; Falk Olbrich; Sabine Samba; R. Dieter Fischer; Paolo Avalle; 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 609 KB

Tetrapropylammonium and -phosphonium ions, nPr 4 E ؉ , react readily with the polymeric super-Prussian blue derivatives [(Me 3 Sn) 3 M(CN) 6 ] (M ‫؍‬ Co, Ir), which are built up of in5nite [ +M+CN+Sn+NC] + chains, a4ording the dimorphic supramolecular assembly [(nPr 4 E)(Me 3 Sn) 2 M(CN) 6 ' 2H 2 O]