## Abstract Structured triacylglycerols with caprylic acid at the __sn__β1 and __sn__β3 positions of the glycerol backbone and eicosapentaenoic acid (EPA) at the position __sn__β2 were synthesised by acidolysis of a commercially available EPAβrich oil (EPAX4510, Pronova Biocare) and caprylic acid c
Production of specific-structured triacylglycerols by lipase-catalyzed reactions: a review
β Scribed by Xuebing Xu
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- English
- Weight
- 269 KB
- Volume
- 102
- Category
- Article
- ISSN
- 1438-7697
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β¦ Synopsis
Production of specific-structured triacylglycerols by lipase-catalyzed reactions: a review
Regiospecificity is one of the major advantages of using lipase technology for the modification of oils and fats to produce high-value added products, such as cocoa butter equivalents, human milk fat substitutes, and other specific-structured lipids. Due to the high cost of biocatalysts, the mainstream applications of lipases for normal oils and fats are still limited. Therefore, positional specificity of lipases has the priority and will be the target property to be exploited for commercial and industrial developments, because no chemical method has such a specificity and is promising or possible for this task. In this paper, encouraging products resulting from this regiospecificity are reviewed together with the critical evaluation of their reaction schemes, side reactions and by-products, sources of substrate oils and acyl donors, and production processes.
π SIMILAR VOLUMES
The lipase catalyzed enantiomeric resolution of syn-glycol was carried out to confirm the sector method, which can determine the absolute configuration of anti-and syn-glycol from the 1 H-NMR spectra of bis-2-methoxy-2-trifluoromethyl-2phenylacetic acid (MTPA) esters. The lipase catalyzed transester