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Production of singlet oxygen in electrogenerated radical ion electron transfer reactions

✍ Scribed by Mayeda, Edward A.; Bard, Allen J.


Book ID
125942101
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
488 KB
Volume
95
Category
Article
ISSN
0002-7863

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The correlation of the reactive component of the bimolecular quenching rate constant, k r , with DG for reactions of singlet molecular oxygen with phenols is interpreted in terms of classical and semiclassical theories of electron transfer. Both treatments indicate a diabatic process with a reorgani