Production of large sodium clusters (Nax,.x⩽65) by seeded beam expansions
✍ Scribed by Manfred M. Kappes; Roland W. Kunz; Ernst Schumacher
- Book ID
- 103022361
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 636 KB
- Volume
- 91
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
✦ Synopsis
Seeded beam cxpans~ons of high-tcmpcrarurc sodmm vapour in hchum, neon, argon, bryplon and mtrogcn carr~cr gase% are elamincd Photoionuatlon coupled with mass spectroscopic dctectlon IS used to dcicrmmc beam constituents Contrary to non-secdcd supcrsoruc ckpansions, m whch the abundance of sodmm clusters obscrvcd dccrcascs c\poncnttily wvlrh IIIcrcasmg cluster SIX. large abundances of hlghcr clusters (Nax, x 6 65) arc observed Lla\una ccntcrcd at m/z = 16 I, tn/z = 437 and nr/z = 874 occur under certain condltlons * Prcscnt address' lnst~tute for Orgamc Chemistry, Univcrslty of Zurich,CH-8057 Zurich, Swatzerland.