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Product-state specific observation of Li(32D) quenching collisions with inert-gas atoms

โœ Scribed by G. Ennen; Ch. Ottinger


Publisher
Elsevier Science
Year
1982
Tongue
English
Weight
496 KB
Volume
88
Category
Article
ISSN
0009-2614

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โœฆ Synopsis


Lithium atoms m the 3 'D state wcrc prcpwd by laser irradnllon of lithmm vapor. Cmissron from scvcn other stews was observed, resulting from coIlmona electronic energy transfer. From depcndencc on argon and tenon gas pressure, &k-toslate rate constants acre delcrmmcd Energy transfer by colbs~ons with ground-&k Llhrum atoms ws also obscrvcd.


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The reaction Ar+(2Pgn) + N,(X tzk,, u = 0) -Ar + Nt(X zag, u") was studred at 1.1 eV coU~~~on energy usmg a crossed-beam method. in contrast wrth results at higher and lower cok~on energtes. the scattenng diagram obtruned at thts energy exhtbtts clearly resolved structure whtch suggests that product