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Product evidence for an enamine mechanism in the acid-catalyzed cleavage of .beta.-amino alcohols. Independence of mechanism on nature of acid

โœ Scribed by Fine, Stephen A.; Shreiner, Jeffrey


Book ID
121245083
Publisher
American Chemical Society
Year
1974
Tongue
English
Weight
454 KB
Volume
39
Category
Article
ISSN
0022-3263

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Mechanism of Azo Coupling Reactions XXXI
โœ Rafal Kaminski; Urs Lauk; Peter Skrabal; Heinrich Zollinger ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› John Wiley and Sons ๐ŸŒ German โš– 879 KB

## Abstract Azo coupling of 6โ€aminoโ€4โ€hydroxyโ€2โ€naphthalenesulfonic acid **(1)** with 3โ€trifluoromethylโ€ and 4โ€nitrobenzenediazonium ion in relative highly concentrated aqueous alkaline solutions gave ratios of aminoazo to hydroxyazo compounds which are much higher than expected on the basis of the