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Product energetics of the reaction C(1D) + H2 → CH + H

✍ Scribed by Gregory M. Jursich; John R. Wiesenfeld

Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
538 KB
Volume
110
Category
Article
ISSN
0009-2614

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✦ Synopsis

PRODUCT ENERGETICS OF THE REACTION C('D) + H, --f CH + H The product CH radic;li of the subject reaction NYIS rnonitorod by hscr-induced ftuorcsccnce following vxuuln ultra-vi&l plwtolysis of C302. As cspccted from consideration of reaction cnerpcIics, only the ground vibrntionnl Icvcl was obsxwd. Th rorarionnl popularion distribution in CH( v" = 0) rmrcks nxll D calculnrcd RRHO prior dislriburion which is ;I\ cragcd over a 300 IL Dolrzu~ann disrriburion ofavaiiablc rcacranr energy. Lie cspcrinlcnral rcsutts are compared 10 roratioml popuhIion distributions derived from previously reported classical trajectory calculations.

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