Processability, mechanical properties, and electrical conductivities of carbon black-filled ethylene-vinyl acetate copolymers

✍ Scribed by Jan-Chan Huang; Chin-Long Wu

• Publisher: John Wiley and Sons
• Year: 2000
• Tongue: English
• Weight: 158 KB
• Volume: 19
• Category: Article
• ISSN: 0730-6679
• DOI: 10.1002/(sici)1098-2329(200022)19:2<132::aid-adv6>3.0.co;2-b

✦ Synopsis

The objective of this study was to investigate the processability, mechanical properties, and electrical properties of carbon black-filled ethylenevinyl acetate (EVA) copolymers with different melt flow indexes (MFIs) and vinyl acetate (VA) contents. The effects of carbon black on maximum temperature, equilibrium torque, equilibrium viscosity, and work energy were characterized in a Haake torque rheometer. These properties were found to increase with an increase in carbon black concentration. MFI was found to be the important factor in determining processing properties of the three different EVA resins. Mechanical properties, including tensile modulus, tensile strength at break, and elongation at break were evaluated and the results showed that tensile modulus was dominated by VA content. MFI was the primary factor influencing tensile strength and elongation at break. Volume and surface resistivity of blends were also studied. EVA with higher MFI and higher crystallinity provided a lower percolation concentration. Bound polymer could be used to explain the differences in viscosity and percolation between EVAs at different molecular weights.