✦ LIBER ✦

Process integration of H2O2 generation and the ammoximation of cyclohexanone

✍ Scribed by Xinhua Liang; Zhentao Mi; Yaquan Wang; Li Wang; Xiangwen Zhang; Wei Wu; Enze Min; Songbao Fu

Publisher: Wiley (John Wiley & Sons)
Year: 2004
Tongue: English
Weight: 93 KB
Volume: 79
Category: Article
ISSN: 0268-2575
DOI: 10.1002/jctb.1037

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

The possibility of the integration of the processes of H~2~O~2~ generation through isopropanol partial oxidation and ammoximation of cyclohexanone with H~2~O~2~ and NH~3~ TS‐1 catalysed was investigated. The ammoximation of cyclohexanone over TS‐1 with isopropanol as solvent was first studied. The results show that isopropanol can be used as solvent, and the impurities in the H~2~O~2~ solution obtained through isopropanol oxidation with only acetone needing to be separated have no harmful effects on the ammoximation of cyclohexanone, suggesting that the process of H~2~O~2~ generation through isopropanol oxidation and the ammoximation of cyclohexanone could be directly integrated. Copyright © 2004 Society of Chemical Industry

📜 SIMILAR VOLUMES

An Integrated Process of H2O2 Production

An Integrated Process of H2O2 Production through Isopropanol Oxidation and Cyclohexanone Ammoximation

✍ X. Liang; Z. Mi; Y. Wang; L. Wang; X. Zhang; T. Liu 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 71 KB

Ammoximation of methyl ethyl ketone with

Ammoximation of methyl ethyl ketone with H2O2 and ammonia over TS-1

✍ Li Wang; Jie Zhang; Zhentao Mi 📂 Article 📅 2006 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 82 KB

## Abstract The ammoximation of methyl ethyl ketone and hydrogen peroxide to form methyl ethyl ketoxime was studied over zeolites (TS‐1) in the temperature range 308–373 K. The reaction was carried out in a batch autoclave at autogenous pressure. The conversion of methyl ethyl ketone and the select

Crystal Structure and Dehydration Proces

Crystal Structure and Dehydration Process of Li(H2O)4B(OH)4 · 2H2O

✍ M. Touboul; E. Bétourné; G. Nowogrocki 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 244 KB

Analysis and Comparison of Absorption Pr

Analysis and Comparison of Absorption Processes in the MgO—SO2—H2O and in the Ca2+—SO2—H2O System

✍ Tadej Recelj; Janvit Golob 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 German ⚖ 46 KB 👁 2 views

Non-isothermal kinetics of the dehydrati

Non-isothermal kinetics of the dehydration process of Na2MoO4·2H2O

✍ Jian-Jun Zhang; Xiu-Fang Zhang; Ke-Zhong Wu; Ning Ren; Xue Zhou; Xiao-Di Liu 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 314 KB

Generation of high O2 (a1Δg) concentrati

Generation of high O2 (a1Δg) concentrations in O2/H2 mixtures

✍ Kangyan Du; Ole Krogh; D. W. Setser 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 105 KB

## Abstract The effect of hydrogen on the concentration of singlet oxygen in the a^1^Δ~g~ and b^1^Σ states, generated from a microwave discharge in O~2~ and in an O~2~/Ar mixture, was studied in flow reactors. The addition of hydrogen, in a range of 0.01–1 of concentration of the O~2~, increased th