Problems in applying classical models to the study of shear vibrations in complexes containing a heavy central atom

The distribution of intensities in a vib

The distribution of intensities in a vibrational spectrum: a model computational study of the transition to classical chaos

✍ J. Brickmann; Y.M. Engel; R.D. Levine 📂 Article 📅 1987 🏛 Elsevier Science 🌐 English ⚖ 657 KB

A model Hamiltoman for two coupled oscillators is used to generate Franck-Condon factors corresponding to transitions between two displaced potential energy surfaces. The distribution of intensities is examined as a function of the energy of the initial state. The fluctuations in the intensities abo