An algcbralc approach IO try-and poly-atomic molcculcs IS prcscnhzd This approach IS appbcd 10 the stud) of Imear ITI-Jtomlc molcculcs It IS sueestcd that these trchnlques ma) be useiul III the desnlptlon of complc\ molecular rotatlonvibrarlon specKI
Problem of intercollisional correlation in vibration-rotation spectra of molecules
✍ Scribed by A.P. Galtsev; M.N. Kuznetsov
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 995 KB
- Volume
- 53
- Category
- Article
- ISSN
- 0022-4073
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📜 SIMILAR VOLUMES
For the vibration-rotational motion of a diatomic molecule, various forms of an effective Hamiltonian which includes the corrections of the Born-Oppenheimer approximation in the form of radial functions are reviewed. A procedure to fit vibration-rotational and pure rotational transitions is proposed
The potential model of G. Thompson et al. [J. Mol. Spectrosc. 124, 130-138 (1987)] for an analysis of the vibrational-rotational and the rotational spectra of diatomic molecules is modified by an algebraic WKB treatment of the Schro ¨dinger equation given by Watson's effective Hamiltonian. A compact
The commutator perturbation method, an algebraic version of the Van Vleck-Primas perturbation method, expressed in terms of ladder operators, has been applied to solving the eigenvalue problem of the Hamiltonian describing the vibrational-rotational motion of a diatomic molecule. The physical model