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Probing the Mechanism of the Baylis–Hillman Reaction by Electrospray Ionization Mass and Tandem Mass Spectrometry

✍ Scribed by Leonardo Silva Santos; Cesar Henrique Pavam; Wanda P. Almeida; Fernando Coelho; Marcos N. Eberlin


Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
221 KB
Volume
116
Category
Article
ISSN
0044-8249

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The behaviour of 5-methyl-2'-deoxycytidine (m 5 dCyd, claimed to be a potential marker for leukaemia) during the electrospray process was studied. In particular, considerations concerning the effect of solution chemistry (e.g. analyte concentration, pH, etc.) on electrospray ionization mass spectra