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Probing the Local Environment of Ti3+ Ions in TiO2 (Rutile) by 17O HYSCORE

โœ Scribed by Dr. Stefano Livraghi; Sara Maurelli; Dr. Maria Cristina Paganini; Dr. Mario Chiesa; Prof. Elio Giamello


Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
325 KB
Volume
123
Category
Article
ISSN
0044-8249

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Single crystals of Ba 6 Fe 45 Ti 17 O 106 and BaFe 11 Ti 3 O 23 were obtained as major and minor coproducts, respectively, by slowcooling an off-stoichiometric BaO:Fe 2 O 3 :TiO 2 melt. The former compound exhibits variable stoichiometry, Ba 6 Fe 48ุŠx Ti 14ุ‰x O 106 , with the Fe:Ti ratio dependent u