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Probing the Formation of Bicyclo[4.2.0]octan-1-ols

โœ Scribed by Loughlin, Wendy A.; Rowen, Catherine C.; Healy, Peter C.


Book ID
127232406
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
157 KB
Volume
69
Category
Article
ISSN
0022-3263

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Synthesis of bicyclo[4.2.0]octan-2-ol, a
โœ Minoru Isobe; Supaporn Niyomchon; Chia-Yi Cheng; Anuch Hasakunpaisarn ๐Ÿ“‚ Article ๐Ÿ“… 2011 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 829 KB

A sesterterpenoid solanoeclepin A (1) has a unique structure including a bicyclo[4.2.0]octane substructure, for which a new synthetic methodology is explored particularly to cyclize functionalized cyclobutane rings. An optically active (R)-carvone and a racemic cyclohexenone were each converted into