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Probing the Electronic and Structural Properties of the Niobium Trimer Cluster and Its Mono- and Dioxides: Nb 3 O n − and Nb 3 O n ( n = 0−2) †

✍ Scribed by Zhai, Hua-Jin; Wang, Bin; Huang, Xin; Wang, Lai-Sheng


Book ID
120205739
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
741 KB
Volume
113
Category
Article
ISSN
1089-5639

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A new niobium oxynitride Nb 2 N 0.88 O 0.12 has been synthesized by reducing Nb 2 O 5 in a stream of H 2 gas containing 0.07% N 2 at 10803C for 5 weeks. The compound crystallizes in a hexagonal system with space group P3 1m, and Z ‫؍‬ 3. The lattice parameters are a ‫؍‬ 5.2916$0.0001 A s and c ‫؍‬ 4