✦ LIBER ✦

Probing the distribution of low symmetry fields by the magnetic field effect on a persistent spectral hole in the R1 line of chromium(III)-tris (2, 2′-bipyridine) in glycerol

✍ Scribed by H. Riesen; E. Krausz; L. Dubicki

Publisher: Elsevier Science
Year: 1994
Tongue: English
Weight: 522 KB
Volume: 218
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(94)00012-3

No coin nor oath required. For personal study only.

✦ Synopsis

The effect of an applied magnetic field on a spectral hole burned in the R, line of [ Cr(bpy),]'+/glycerol is measured. The hole spreading observed deviates considerably from a behaviour expected for a trigonal system. A model taking into account a distribution of low symmetry fields provides far better agreement with experiment. The same approach was previously applied to describe the large variation of the *E splitting in various amorphous systems.