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Probing Surface Sites of TiO2: Reactions with [HRe(CO)5] and [CH3Re(CO)5]

✍ Scribed by Rodrigo J. Lobo-Lapidus; Bruce C. Gates


Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
401 KB
Volume
16
Category
Article
ISSN
0947-6539

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## Me3P Me3P PMe, 1 2 3 stereoisomers which display hydride/PMe, cis-and hydride/CO trans-configurations. The syntheses of 2 and 3 were recently reported [5], and 1 was obtained in high yield by reduction of [ReCl(CO),(PMe,),] with Na in THF and subsequent acidification with H,O. Out of the seri