Probing macrocycle flexibility: ligand binding to zinc and nickel tetraphenylhydroporphyrins
✍ Scribed by Kaplan, Warren A.; Scott, Robert A.; Suslick, Kenneth S.
- Book ID
- 121484797
- Publisher
- American Chemical Society
- Year
- 1990
- Tongue
- English
- Weight
- 412 KB
- Volume
- 112
- Category
- Article
- ISSN
- 0002-7863
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📜 SIMILAR VOLUMES
Nickel(II) complexes of mono-and bis(macrocyclic) ligands are the products of a nickel(II)-assisted template reaction with 2,3,2-tet, melamine and formaldehyde [2,3,2-tet = bis-N,NЈ-(2-aminoethyl)propane-1,3-diamine; melamine = 2,4,6-triamino-1,3,5-triazine]. The structures of two four-coordinate, d
## Abstract The reactivity of the two nickel complexes [Ni(xbsms)] and [Ni(bsms)~2~] [H~2~xbsms = α,α′‐bis(4‐mercapto‐3,3‐dimethyl‐2‐thiabutyl)‐__o__‐xylene; Hbsms = 4‐mercapto‐3,3‐dimethyl‐1‐phenyl‐2‐thiabutane] towards copper iodide and zinc bromide has been investigated. The reactions yield nove