Principle of corresponding states of liquid solutions—excess enthalpy and the pseudocriticals
✍ Scribed by R.A. Mentzer; K.L. Young; R.A. Greenkorn; K.C. Chao
- Publisher
- Elsevier Science
- Year
- 1978
- Tongue
- English
- Weight
- 805 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0009-2509
No coin nor oath required. For personal study only.
✦ Synopsis
A new generalized enthalpy function of low pressure saturated liquids IS developed to permit the accurate calculation of heats of nuxmg from the known pseudo quantrtles of a mixture system A procedure IS developed, with the ald of the new entbalpy function, by which o' and T: of bmary nuxtures are determined from experunental heat of mixing data of their liquid solutions at multiple temperatures The procedure IS applied to twenty-seven binary hydrocarbon systems for whxh data were found m the literature The pseudo quantrtles are
📜 SIMILAR VOLUMES
Experimental surface-tension data for pure substances have been correlated successfully by the use of two recent modifications of the principle of corresponding states. The results are expressed in terms of simple analytical relations which allow one to calculate the surface-tension curves either fr
A new method of studying orientational correlations in liquids of linear molecules is presented and applied to Nz, Fl, Cl,, Br,, Is, CO\* and C& near their triple points. The method is based on the subdivision of the total angular space of a pair of molecules into a complete set of disjoint classes