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Primary structure of the 2-O-methyl-α-l-fucose-containing side chain of the pectic polysaccharide, rhamnogalacturonan II

✍ Scribed by John N Glushka; Mark Terrell; William S York; Malcolm A O'Neill; Angela Gucwa; Alan G Darvill; Peter Albersheim; James H Prestegard


Book ID
108309429
Publisher
Elsevier Science
Year
2003
Tongue
English
Weight
485 KB
Volume
338
Category
Article
ISSN
0008-6215

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Methyl 4-azido-4,6-dideoxy-3-O-benzyl-ct-D-mannopyranoside and its analogous 3-O-(4methoxybenzyl) derivative were methylated and the 2-O-methyl derivatives formed were convetted into methyl 4-amino-4,6-dideoxy-2-O-methyl-a-o-mannopyranoside. Reaction of the latter with 3-deoxy-L-glycero-tetronolacto