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Primary and secondary kinetic isotope effects as transition state criteria in nucleophilic substitution and elimination reactions

โœ Scribed by P.J. Smith; K.C. Westaway

Publisher
Elsevier Science
Year
1988
Weight
79 KB
Volume
39
Category
Article
ISSN
0883-2889

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The kinetics of the gas phase intramolecular elimination of isobutene from 2-d1-triisobutylaluminum and the deuterium isotope effect in reactions involving cyclic transition states
โœ Kurt W. Egger ๐Ÿ“‚ Article ๐Ÿ“… 1969 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 654 KB

The intramolecular elimination of isobutene from 2-d,-triisobutylaluminum has been studied in the gas phase for temperatures ranging between 102.4 and 184.6'C. The reaction is apparently homogeneous and obeys the first order rate law, yielding the following Arrhenius relationship: log kelim (sec-')